I think the only way you can do this now is to do a SendKeys() on the ListView item.

Give this a try...

code:
FOR EACH $Item IN $List.Items
$Item.SetFocus
$nul=SendKeys({right})
$RC = IsPing($Item.SubItems(0).Text)
$PingError = @error
SELECT
CASE $PingError = 0
$PingStatus = 'On'
CASE $PingError = 1
$PingStatus = 'RAS'
CASE $PingError = 2
$PingStatus = 'Off'
CASE $PingError = 3
$PingStatus = 'Gone'
CASE 1
$PingStatus = 'PROBLEM'
ENDSELECT
$Item.SubItems(1).Text = $PingStatus
$Item.SubItems(2).Text = $AddressIP
$Item.SubItems(3).Text = $AddressName
$Item.SubItems(4).Text = $IPError
NEXT