well, instead of "documents and..." use the env variable: %userprofile%...

ah, quick rewrite to see if there is more errors...
code:
If INGROUP("KS1")
del "%userprofile%\DESKTOP\*.*"
copy "\\SCHOOLNT\KS1DESKTOP\*.*" "%userprofile%\DESKTOP"
AT(3,4) "KS1"
ENDIF

If INGROUP("KS2")
del "%alluserprofile%\DESKTOP\*.*"
copy "\\SCHOOLNT\KS2DESKTOP\*.*" "%alluserprofile%\DESKTOP"
AT(3,4) "KS2"
ENDIF

AT(5,4) "RAN"

what about that...
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