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Ahhh ok - Interesting...
Windows added the "sysvol\..\{GUID}\.." thingy path to the BEGINNING of your PATH environment variable !
The other interesting setting is this:
USERPROFILE=D:\Documents and Settings\Default User
Having said that - a lot of settings are missing, like USERDOMAIN and USERNAME, HOMEDRIVE, HOMEPATH etc ... not totally un-expected I guess. We are running in the system context.
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