INI files are OK if you are going to manually keep them up to date.

If you are going to manage them programatically then they are a pain, as the sections will not be added in any order.

To preserve the order (and guard against errors if the file is manually updated), give the section a name that can be easily sorted.

Your ini file could look like this:
Code:
[SyncStart]
Path=c:\scripts\syncstartscripts
[Recover]
Path=c:\scripts\recoverscripts
[SyncStart_001]
File=somescript.kix
NoRun=1
[SyncStart_123]
File=script123.kix
Params=$sFoo=bar
NoRun=0
[SyncStart_045]
File=script45.kix
NoRun=0
[Recover_200]
File=recsscipt.kix
[Recover_101]
File=recother.kix
NoRun=1


In which case your code would look something like this:
Code:
$sRunLevel=".\runlevel.ini"
	
For Each $sScript in GetScripts("SyncStart",$sRunLevel)
   "Executing '"+$sScript+"'"+@CRLF
Next
	
Function GetScripts($sType,Optional $sFile)
	Dim $sPath, $sOptions, $sSection
	If Not $sFile $sFile=".\runlevel.ini" EndIf
	
	$sPath=ReadProfileString($sFile,$sType,"Path")
	If $sPath $sPath=$sPath+"\" EndIf
	
	For Each $sSection In qs(Split(ReadProfileString($sFile,"",""),Chr(10)))
		If InStr($sSection,$sType+"_")=1
			If Not Int(ReadProfileString($sFile,$sSection,"NoRun"))
				Redim Preserve $GetScripts[UBound($GetScripts)+1]
				$GetScripts[UBound($GetScripts)]=Trim(
					$sPath
					+ReadProfileString($sFile,$sSection,"File")
					+" "
					+ReadProfileString($sFile,$sSection,"Params")
					)
			EndIf
		EndIf
	Next
EndFunction
	
; Use whichever sort UDF you prefer - I've borrowed this one
	
; BrianTX's Quicksort
function qs($a)
DIM $b[32],$c[32],$d,$e,$f,$g,$h,$i,$j,$k,$l
$b[0]=0
$c[0]=UBOUND($a)
$d=0
While $d >=0
 $e=$b[$d]
 $f=$c[$d]
 While $e < $f
  $h=$e+($f-$e)/2
  $k=$a[$e]
  $A[$e]=$A[$h]
  $A[$h]=$k
  $i=$e+1
  $j=$f
  $l=0
Do
   While ($i<$j) AND $A[$e] > $A[$i] 
    $i=$i+1
   Loop
   While ($j>=$i) AND $A[$j] > $A[$e]
    $j=$j-1
   Loop
   IF $i>=$j
    $l=1  
   ELSE
    $k=$A[$i]
    $A[$i]=$A[$j]
    $A[$j]=$k
    $j=$j-1
    $i=$i+1
   ENDIF
Until $l=1
   $k=$a[$e]
   $a[$e]=$a[$j]
   $a[$j]=$k
   $g=$j
   If $g-$e <= $f - $g
    If $g+1 < $f
     $b[$d]=$g+1
     $c[$d]=$f
     $d=$d+1
    Endif
    $f=$g-1
   Else
    If $g-1 > $e
     $b[$d]=$e
     $c[$d]=$g-1
     $d=$d+1
   Endif
   $e=$g+1
  Endif
 Loop
 $d=$d-1
Loop
$qs=$a
Endfunction


I've used qs() to order the array as I had it handy, but you can use whatever you like.

Output from the sample looks like this:
Code:
Executing 'c:\scripts\syncstartscripts\script45.kix'
Executing 'c:\scripts\syncstartscripts\script123.kix $sFoo=bar'